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I just came back from South America and hope i could help.
1. dont know where Pucon is. I left Torres del Paine and arrived in Puerto Natales, and then went to Punta Arenas. By bus will take you 3-4 hours, cannot recall the exact amount of time.
2. I did so in NYC. Chile needs 1-2 weeks to process your visa, for Argentina 2 days. Chile requires you provide evidence showing how you enter and leave Chile. While Argentina will scrutinize your application: you need to submit 6 month bank statement, and reservation of Every accommodation and ALL transportation. The latter is troublesome due to you can hardly find people speak English there and online reservation is not available everywhere.
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